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31.
The occurrence of trace metals was studied at the interface between groundwater and the drainage system of a large floodplain in NE Germany, the Oderbruch region. Depending on the predominant hydraulic connectivity between groundwater and the drainage channels, the geochemical environment creates a high variability in the accumulation of Fe, Mn, Cd, Zn, Cu, and As. The mobility of the trace metals depends on spatial variable redox transition zones which act as geochemical barriers between the anaerobe aquifer and the oxic surface waters. In drainage ditches with high exchange flow between groundwater and surface water the transition zone is small and unstable with a low retention potential for trace metals. Decreasing hydraulic gradients and respectively decreasing base flow cause the change for an extensive transition zone with increasing trace metal accumulation in the channel sediments. The accumulation is mainly controlled by oxidation and degassing of CO2. In the streambed sediments of channels which periodically run dry an effective chemical barrier can be observed. This Fe dominated oxic horizon controls the accumulation of Mn > Cu > As > Zn > Cd, which are mainly associated with fresh, amorphous Fe oxyhydroxides. The chemical barriers can be instable and reversible. Therefore, water management decisions are discussed which stabilize the barriers by controlling aquifer-channel exchange rates, channel oxygen content and surface water levels.  相似文献   
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The John’s creek valley (Johnsbachtal) is presented as a long-term, interdisciplinary cooperation platform in upper Styria (Austrian Alps) that brings together the interests and knowledge of persons with different backgrounds (scientists, teachers, students, as well as local actors and the population) with the central aim to generate mutual benefit for all involved parties. It covers an area of around 65 km2 with elevations between 600 and 700 m in the valley to over 2,300 m in the summit regions. Annual mean temperature ranges from approximately 8 °C in the lower elevations of the valley to below 0 °C in the summit regions. Annual precipitation mounts to values of 1,500 mm and more than 1,800 mm in the lower elevations and summit regions, respectively. To allow for a long-term monitoring of the complex meteorological and hydrological conditions in the area, a hydroclimatological monitoring network has been installed that is described in detail in this paper. A special characteristic of the installed meteorological stations is that they cover a large range of altitudes and, therefore, allow to capture the gradients in meteorological variables induced by the complex Alpine topography. Furthermore, the hydroclimatological monitoring network in John’s creek valley is largely independent of regular third-party project funding, and therefore, not temporarily limited in its existence. A number of catchment research activities that cover a variety of disciplines (e.g., climatology, hydrology, (hydro)geology, geomorphology) and that largely benefit from the hydroclimatological data recorded in John’s creek valley are presented together with preliminary results. The latter include spatial distributions of meteorological and hydrological variables (e.g., precipitation, evapotranspiration and snowmelt) calculated for the test site using the hydrometeorological model AMUNDSEN. Furthermore, the results of hydrogeological investigations that have been carried out at the Etzbach spring are presented and discussed.  相似文献   
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Abstract

The Upper Prealpine nappe of the Swiss and French Prealps consists of a composite stack of various tectonic slivers (Gets, Simme, Dranse and Sarine sub-nappes, from top to bottom). The structural superposition and stratigraphic content of the individual sub-nappes suggests a successive stacking at the South Penninic/Adriatic transition zone during the Late Cretaceous and Early Paleogene. The present paper deals with two aspects. (1) new data obtained from the Complexe de base Series of the Dranse sub-nappe which underlies the Helminthoid Sandstone Formation, and (2) the development of a geodynamic accretionary model for the Upper Prealpine nappe stacking.

The Complexe de base Series reveals a succession of black shales at the base, grading upward into variegated red/green and red shales which were deposited in an abyssal plain environment starved of clastic input. It is overlain by the Helminthoid Sandstone Formation. The combined analysis of planktic and agglutinated benthic foraminifera and comparisons with other Tethyan series suggest an Albian to Campanian age of the Complexe de base succession. Tectonic transport of the abyssal plain segment into a trench environment allowed for the stratigraphic superposition by the Helminthoid sandstone sequence. The present findings combine well with the general scheme of the Upper Prealpine nappe stack and several single results on parts of the nappe stack. We take that opportunity to present a comprehensive model for the tectono-sedimentary evolution of the Upper Prealpine nappe.

We suggest that Late Jurassic-Early Cretaceous asymmetric (?) extension at the South Penninic-Adriatic margin created an extensional alloehthon. Later during the mid-Cretaceous, the start of convergence drove the obduction of oceanic crust on the northern margin of the extensional allochthon. The resulting ophiolitic/continental source supplied clasts to the trench basin in front (Manche turbidite series), and the backarc basin (Mocausa Formation) and abyssal plain (Perrières turbidite series) to the South. During Middle to Late Coniacian the main Adriatic margin was thrusted over the obductionrelated mixed belt and established an incipient accretionary prism containing the former trench, backarc and abyssal plain basin fill series. During this stage the Gueyraz (melange) Complex formed, which separates the trench series from the retroarc and abyssal plain formations. On top of the incipient accretionary prism a forearc basin developed hosting the Hundsrück Formation. The frontal abyssal plain formation (Complexe de base) still received few turbiditic intercalations. From Campanian time on, the forearc basin was bypassed and deposition of the Helminthoid Sandstone Formation occurred on the Complexe de base succession. During the Maastrichtian the abyssal plain and trench fill succession (Dranse nappe) was accreted to the incipient wedge, and in front of a newly active buttress, the Gurnigel trench basin was established. Another accretionary event during latest Paleocene/earliest Eocene added parts of that trench series to the base of the wedge (Sarine nappe). During the Late Eocene the accretionary wedge and remaining trench fill series (Gurnigel nappe) were thrusted en-bloc over the Middle Penninic limestone nappes and partly overtook the latter. Continued shortening of the resulting nappe pile and out-of-sequence thrusting accomplished the overriding of the Middle Penninic units over the former South Penninic Gurnigel trench series (inversion of palaeogeographic domains).  相似文献   
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The crystal structures, lattice dynamics and magnetic properties of synthetic Co-cordierite, Co2Al4Si5O18, and Mn-cordierite, Mn2Al4Si5O18 have been studied by neutron powder diffraction, infrared spectroscopy and magnetisation measurements. Due to different synthesis conditions, the Co-cordierite used here crystallised in the hexagonal α-cordierite structure with a disordered Si/Al distribution in the framework, while for the Mn-cordierite the orthorhombic β-structure has been determined. The experimentally determined paramagnetic moments, exp (Mn) = 5.47(6) B and exp (Co) = 3.88(4) B , are in good agreement with theoretical predictions for octahedrally coordinated Mn2+ and Co2+, respectively. In both compounds there is no magnetic long-range order down to at least 1.5 K. However, the onset of an anti-ferromagnetic short-range correlation of magnetic moments along [001] has been observed for Mn-cordierite by magnetisation and neutron diffraction measurements. This short-range magnetic correlation becomes evident from diffuse scattering observed at 2 K. The diffuse scattering has been interpreted in terms of a Blech-Averbach function. Received: 30 June 1998 / Revised, accepted: 3 March 1999  相似文献   
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Periods of summertime low flows are often critical for fish. This study quantified the impacts of forest clear‐cutting on summertime low flows and fish habitat and how they evolved through time in two snowmelt‐dominant headwater catchments in the southern interior of British Columbia, Canada. A paired‐catchment analysis was applied to July–September water yield, the number of days each year with flow less than 10% of mean annual discharge, and daily streamflow for each calendar day. The postharvest time series were divided into treatment periods of approximately 6–10 years, which were analysed independently to evaluate how the effects of forestry changed through time. An instream flow assessment using a physical habitat simulation‐style approach was used to relate streamflow to the availability of physical habitat for resident rainbow trout. About two decades after the onset of logging and as the extent of logging increased to approximately 50% of the catchments, reductions in daily summertime low flows became more significant for the July–September yield (43%) and for the analysis by calendar day (11–68%). Reductions in summertime low flows were most pronounced in the catchment with the longest postharvest time series. On the basis of the temporal patterns of response, we hypothesize that the delayed reductions in late‐summer flow represent the combined effects of a persistent advance in snowmelt timing in combination with at least a partial recovery of transpiration and interception loss from the regenerating forests. These results indicate that asymptotic hydrological recovery as time progresses following logging is not suitable for understanding the impacts of forest harvesting on summertime low flows. Additionally, these reductions in streamflow corresponded to persistent decreases in modelled fish habitat availability that typically ranged from 20% to 50% during the summer low‐flow period in one of the catchments, suggesting that forest harvest may have substantial delayed effects on rearing salmonids in headwater streams.  相似文献   
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Climate change is anticipated to influence all parts of agricultural production systems. However, the potential impacts on crop storage have rarely been assessed, even though storage is an important component of a grower’s marketing strategy and is essential for the continuous supply of a commodity for processors, exporters, and consumers. The Michigan chip-processing potato industry provides an example of the importance of crop storage. Michigan is the largest producer of chip-processing potatoes in the USA, and potatoes are stored on farms from September to June. We use an ensemble of climate projections developed for three future time slices (early, mid, and late century) from 16 climate models forced by three greenhouse gas concentration pathways to assess future changes in potato storage conditions. Our findings indicate an increased future demand for ventilation and/or refrigeration immediately after harvest and again in spring and early summer, even for the early-century time slice. Furthermore, the period of reliably cold storage temperatures during winter is anticipated, when averaged across all models, to shorten by 11–17 days in Michigan’s primary production area and 14–20 days in the more southern secondary area by mid-century, and by 15–29 days and 31–35 days, respectively, for the northern and southern production areas by late century. The level of uncertainty, as indicated by the ensemble range, is large, although the sign of the projected changes in storage parameters is consistent. This case study provides an example of the potentially large effects of climate change on the storage conditions for agricultural commodities.  相似文献   
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